A New Method for the Quantitative Determination of Sulfate Ions in Aqueous Extracts from Soils and in Aqueous Media, and Analytical Equipment for Its Implementation
Yuri Loginov,
Vladimir Kuznetsov
Issue:
Volume 11, Issue 1, March 2023
Pages:
1-8
Received:
21 November 2022
Accepted:
14 January 2023
Published:
14 February 2023
Abstract: A method and the necessary analytical equipment for the mass quantitative determination of sulfate ions in aqueous extracts from soils and in aqueous media is proposed, consisting in the fact that a known amount of 2-aqueous barium chloride with hydrogen chloride is added to the aliquot of the analyzed sample in the form of an aqueous solution. The resulting insoluble barium sulfate compound reduces the initial concentration of barium chloride. The amount of barium chloride remaining in the solution is determined on the specially designed flame spectrophotometric analyzer. This allows you to calculate the amount of sulfate ions associated with barium, which is automatically performed by the device program. The range of reliably determined concentrations of sulfate ions by the proposed method in water samples ranged from 10 to 100 mg/dm3. The range of reliably determined concentrations of sulfate ions in aqueous extracts from soils ranged from 0.2 to 2.4 C(1/2SO4) mol/dm3 (from 10 to 115 mg/dm3). Higher concentrations of sulfate ions must be diluted multiple times with distilled water. The method makes it possible to determine the concentration of sulfate ions in aqueous soil extracts, freshwater reservoirs and rivers, underground sources, tap water, sediments contaminated with sulfuric acid emissions from industrial enterprises. The method is quite simple, accurate and productive. The method is certified by the State Ural Research Institute of Metrology (MVI-66373620-007-2018) and approved by the Federal Agency for technical regulation and Metrology (Rosstandart), as a standard method under No. 253.0080/RA. RU.311866/2019. Patent No. 2681855 of the Russian Federal Service for Intellectual Property with priority dated September 15, 2017 was obtained for the method for determining sulfur in the form of a sulfate ion in an aqueous extract from soils and the equipment necessary for this. Detailed methods for determining sulfate ions in these objects are published in the open press in the book: "Determination of agrochemical and chemical parameters of soils, plants and aquatic environments using flow-decade analysis technology" edited by Academician of the Russian Academy of Sciences R. F. Baibekov.
Abstract: A method and the necessary analytical equipment for the mass quantitative determination of sulfate ions in aqueous extracts from soils and in aqueous media is proposed, consisting in the fact that a known amount of 2-aqueous barium chloride with hydrogen chloride is added to the aliquot of the analyzed sample in the form of an aqueous solution. The...
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Chemical Constituents, Proximate Composition, and Heavy Metals of the Oil Seed of Guizotia scabra Consumed in Plateau State-Nigeria
Pam Audu Chomo,
Anya Ezekiel Gyang,
Joyce Bahago Istifanus
Issue:
Volume 11, Issue 1, March 2023
Pages:
9-12
Received:
8 October 2022
Accepted:
10 November 2022
Published:
31 March 2023
Abstract: Guizotia scabra (L. F cass. composite) is an oil seed crop found wildly and in some areas cultivated at middle and higher geographical locations in Nigeria and other African countries. The objectives of this research were to among other things determine the physicochemical properties, proximate composition, and chemical constituents. Standard methods for physicochemical properties, proximate analysis and GC/MS was used to determine the chemical constituents. The physicochemical properties revealed acid value 0.455 mg/KOH/g. The percentage yield was 21.34%. The saponification value was 33.10 mg of KOH/kg. Peroxide value revealed 16.35 meq/KOH/kg. The iodine value was 66.83g/100g. The Specific gravity was 0.9246 and the viscosity was 25.3 mPa.s. A proximate composition 6.95% of moisture content, ash content was 3.05%, crude protein was 21.72%, crude fat was 24.4%, crude fibre was 29.5%, dry matter content was 93.50% and organic matter content was 96.95%. The chemical constituents revealed 9, 12-Octadecadienoic acid (31.80%) as the predominant unsaturated fatty acid in the seed oil while Dodecanoic acid (Lauric acid) (3.46%) is the predominant saturated fatty acid. The concentration of Zn in the samples was (1.146±0.00 µg/g), is higher than the other metals (Cu, Fe, Ni, and Pb), Ni and Pb were not detected in the sample. Guizotia scabra seed oil from Plateau state is therefore good for consumption due to it low acid value, good protein content, good amount of unsaturated fatty acid, low concentration of heavy metals and some phytochemicals.
Abstract: Guizotia scabra (L. F cass. composite) is an oil seed crop found wildly and in some areas cultivated at middle and higher geographical locations in Nigeria and other African countries. The objectives of this research were to among other things determine the physicochemical properties, proximate composition, and chemical constituents. Standard metho...
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